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Open seminar

Lecture Title "Explosives Sensing by Nanoscopic Architectures and Chemical Reactions in Confined Nanospace"
Date Tuesday 11 November 2014 16:00 to 17:30
Lecturer Associate Prof. Partha Sarathi Mukherjee (Department of Inorganic & Physical Chemistry Indian Institute of Science Bangalore, India)
Place

Yamate, Building 3, 2nd floor seminar room
Summary

Engineering discrete molecular architectures of defined shapes and sizes using metal-ligand coordination as driving force is an active field of current research. [1] The architectural advantage of the rigid square-planar coordination environment of Pd(II) and Pt(II) has long been utilized for this purpose. My lecture will focus on the design principle including several examples of electron rich molecular nano-cages that are potential in sensing electron deficient explosives like TNT, DNT etc. [2,3] My lecture will also focus on the self-assembly of water soluble Pd(II) molecular cages and use of their confined nanospace  as molecular vessels to perform several organic transformations in environmental friendly aqueous medium in catalytic manner. Self-sorting in organic cage formation and cage to cage transformations will also be highlighted.
 

References：
1.  Chakrabarty, R.; Mukherjee, P. S.; Stang, P. J. Chem. Rev. 2011,111, 6810.
2.  Ghosh, K.;  Mukherjee, S.; Mukherjee, P. S. J. Am. Chem. Soc. 2013, 135, 554.
3.  (a) Samanta, D.; Mukherjee, P. S. Chem.Commun, 2014, 50, 1595. (b) Gole, B.; Shanmugamraju, S.; Bar, A. K.; Mukherjee, P. S. Chem. Commun. 2011, 47, 10047. (c) Bar, A. K.; Chakrabarty, R.; Mostafa, G.; Mukherjee, P. S. Angew. Chem. Int. Ed. 2008, 47, 8455. (d) Mukherjee, S.; Mukherjee, P. S. Chem. Commun. 2014, 50, 2239. (e) Bar, A. K.; Ragothama, S.; D. Moon; Mukherjee, P. S. Chem. Eur. J. 2012, 18, 3199. (f) Gole, B.; Mukherjee, P. S. Chem. Eur. J. 2014, 20, 2276. (g) Acharyya, K.; Mukherjee, P. S. Chem. Eur. J. 2014, 20, 1646. (h) Samanta, D.; Mukherjee, P. S. Chem. Commun. 2013, 49, 4307. (i) Samanta, D.; Mukherjee, P. S. Chem. Eur. J. 2014, 20, 12483.

 
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Donglin JIANG
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