研究・研究者
研究会・セミナー
| 演 題 | 「Femtosecond Electron Diffraction: "Making the Molecular Movie"」 |
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| 日 時 | 2007年10月31日(水) 16:00 |
| 講演者 | Prof. R. J. Dwayne Miller Dept. of Chemistry and Physics, Institute for Optical Sciences, University of Toronto |
| 場 所 | 分子研 研究棟301号(セミナー)室 |
| 概 要 |
この度、University of Toronto よりProf. R. J. Dwayne Miller を お迎えして、下記のセミナーを開催いたします。
Femtosecond Electron Diffraction harbours great potential for providing atomic resolution to structural changes as they occur, essentially watching atoms move in real time --- directly observe transition states. This experiment has been referred to as "making the molecular movie" and has been previously discussed in the context of a classic gedanken experiment, outside the realm of direct observation. With the recent development of femtosecond electron pulses with sufficient number density to execute nearly single shot structure determinations, this experiment has been finally realized. A new concept in electron pulse generation was developed based on a solution to the N-body electron propagation problem involving up to 10,000 interacting electrons that has led to a new generation of extremely bright electron pulsed sources that minimizes space charge broadening effects. Previously thought intractable problem of determining t=0 and fully characterizing electron pulses on the femtosecond time scale have now been solved through the use of the laser pondermotive potential to provide a time dependent scattering source. Synchronization of electron probe and laser excitation pulses is now possible with an accuracy of 10 femtoseconds to follow even the fastest nuclear motions. The camera for the "molecular movie" is now in hand. Atomic level views of the simplest possible structural transition, melting, have been obtained for a number of metals under strongly driven conditions (up to warm dense matter conditions) under which the dynamics occur over nm or molecular lengths scales. Direct observation of phonon distortions involved in electron-scattering in semiconductors can now be resolved.
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