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第922回分子研コロキウム

演 題 「Atomic-Scale Observations of Catalyst Structures with STM under Reaction
Conditions and during Catalysis」
日 時 2018年07月17日(火) 16:00
講演者 Prof. Franklin (Feng) Tao [The University of Kansas]
場 所

分子科学研究所 研究棟201号室

概 要

Heterogeneous catalysis is a chemical process performed at a solid−gas or solid−liquid interface. Direct participation of catalyst atoms in this chemical process determines the significance of the surface structure of a catalyst in a fundamental understanding of such a chemical process at a molecular level. High-pressure (or called ambient pressure) scanning tunneling microscopy (HP-STM) has been used to observe catalyst structure in the last few decades. I will present instrumentation of high pressure (or called ambient pressure) STM for in situ/operando of model catalyst surfaces and scientific findings on catalyst structures under reaction conditions and during catalysis with the following objectives: (1) to present the fundamental aspects of in situ/operando studies of catalysts; (2) to interpret the observed restructurings of catalyst and evolution of catalyst structures; (3) to explore how HP-STM could reveal structural details under reaction conditions and during catalysis; and (4) to discuss the future challenges and prospects of atomic-scale observation of catalysts in understanding of heterogeneous catalysis.

Reference:
Tao, F. and Crozier P. A. Chem Rev. 2016, 116, 3487.
Tao, F. et al. Science, 2010, 327, 850.

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お問合せ先

所内対応者:横山 利彦(電子構造)
藤 貴夫、椴山 儀恵(2018年度コロキウム委員)